This study analyzed the relationship between the environmental temperature and the number of car accidents from the perspectives of space and time. The environmental temperature was retrieved by satellite images and the car accident records were based on the open data provided by the government open data platform. After sorting out the location data, three grid cells of different sizes were used to calculate the average surface temperature of the city and the number of car accidents. In order to confirm whether other factors are also related to the occurrence of car accidents, we added index related to road types, and analyzed relative asymmetry (RA) indicators through the concept of space syntax using road network diagrams to calculate the integration of the road. After the above pre-processing was completed, the bivariate local indicators of spatial association (BiLISA) and Poisson regression were used to analyze the spatial and non-spatial correlations between the surface temperature and the RA value and the number of accidents. The results help us to clarify whether there is a correlation between the location of the car accident and the urban surface temperature or road pattern. The results showed that both BiLISA and Poisson regression proved that the number of car accidents is positively correlated with the surface temperature, which can be provided to urban planning and local police units for future comprehensive review, urban design, car accident prevention, city appearance arrangement and traffic law enforcement etc. as the reference.