Mapping of surface reflectance has been considered as a primary task for optical remote sensing, since the remotely sensed data is dependent of sensor characteristics, solar-viewing geometry, the atmosphere and topography for a given canopy. In order to retrieve its intrinsic reflective characteristics that is reasonablly indepent of the above external factors, determination of reflectance by using radiometric correction of satellite image is considered to be indispensable. The purpose of the dissertation is radiometric correction of SPOT satellite imagery. Firstly, the variability of surface reflective characteristics due to solar-viewing geometry and the atmospheric haziness is studied. We propose the optimal view angle should be defined as the direction that could be used to estimate the albedo and is insensitive to cover types, solar zenith angle and the optical properties of the atmosphere. Secondly, the atmospheric correction model of satellite image in horizontal surface is proposed. The aerosol characteristics are iteratively retrieved from the image itself. Thirdly, urban bidirectional reflectance distribution function (BRDF) is retrieved by using multi-temporal multiangle SPOT imageries. Fourth, we suggested the normalized reflectance determined by its intrinsic BRDF is much suitable than bidirectional reflectance factor (BRF) as the spectral knowledge. Finally, a robust algorithm for retrieving aerosol optical depth from satellite image over a mountainous area is proposed. The results show that the optimal view angle determined by Kimes and Sellers (1985) would be insensitive to the aerosol optical depth. The RMSE of derived surface reflectance in the horizontal surface is about 0.01-0.02 over reflectance range 0.0-0.6. Spectral knowledge determined from normalized reflectance is much suitable than that proposed by Wharton (1987). Determination of reflectance image can reduce the topographic effect of image mountainous area. Without atmospheric correction, terrain related classes of forest class would be classified from unsupervised classification, whereas they automatically merge to one class after atmospheric correction. Radiometric corrected image is more suitable for change detection analysis than raw image.